PREPARATION OF CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM FROM TRIS(TRIPHENYLPHOSPHINE)CHLORORHODIUM, CARBON DIOXIDE, AND MOLECULAR HYDROGEN

Preparation of Carbon Molecular Sieves from Pistachio Shell and Walnut Shell for Kinetic Separation of Carbon Monoxide, Hydrogen, and Methane

In this study, two Carbon Molecular Sieves using Pistachio shell (CMS P) and Walnut shell (CMS W) were prepared by a chemical vapor deposition method and used for pressure swing adsorption and separation of CO/H2 and CO/CH4. Adsorption isotherms of gases obtained for both CMS’s. The Dubinin-Radushkevich isotherm model was used for comparing pore volum...

Preparation of Graphene-amine Nanofluid for Absorption of Carbon Dioxide (CO2) and Hydrogen Sulfide (H2S) from a Natural Gas Stream in a Wetted Wall Column

    In this study, it was shown that how CO2 and H2S were removed from a natural gas stream, using a nanofluid containing nanoporous graphene in Diehanolamine (DEA). Before running the experiments, the appropriate values were chosen for the nanosheet dosage and the liquid and gas flow rates in the absorption experiments, which were performed in a laboratory scale wetted wall column. In the expe...

Separation of Hydrogen from Carbon Dioxide through Porous Ceramics

The gas permeability of α-alumina, yttria-stabilized zirconia (YSZ), and silicon carbide porous ceramics toward H₂, CO₂, and H₂-CO₂ mixtures were investigated at room temperature. The permeation of H₂ and CO₂ single gases occurred above a critical pressure gradient, which was smaller for H₂ gas than for CO₂ gas. When the Knudsen number (λ/r ratio, λ: molecular mean free path, r: pore radius) of...

Assimilation of carbon dioxide by hydrogen bacteria.

Autotrophic organisms can use carbon dioxide as their sole source of carbon. Within this group, the chemosynthetic bacteria secure energy for carbon dioxide assimilation by the oxidation of simple inorganic substances, although the photosynthetic organisms obtain this energy from light. The phylogenetic relationships of the chemosynthetic bacteria to the photosynthetic and to the heterotrophic ...

Ruthenium-catalyzed direct methylation of primary and secondary aromatic amines using carbon dioxide and molecular hydrogen.